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After downloading an e-mail full of government...

After downloading an e-mail full of government secrets, computer geek Chuck Bartowski is thrust into a career as a secret agent.

While still coming to grips with his new...

While still coming to grips with his new life as a secret agent, Chuck has to figure out if his new partners can be trusted.

Chuck embarks on his first real spy mission...

Chuck embarks on his first real spy mission while trying to juggle the responsibilities of his day job at Buy More.

A hot CIA agent enlists Chuck’s help to...

A hot CIA agent enlists Chuck’s help to retrieve a million-dollar diamond hidden in a mansion before terrorists put it to use.

Chuck faces a tough decision: turn his back...

Chuck faces a tough decision: turn his back on the government and his friends or do what he believes is right in his heart.

Secrets from the past come to light when...

Secrets from the past come to light when Chuck returns to his university to help out the same professor that expelled him.

Chuck learns a lot about his partners after...

Chuck learns a lot about his partners after a poison specialist uses a truth serum to gain entry codes to a nuclear facility.

Chuck’s girlfriend may not be who she seems...

Chuck’s girlfriend may not be who she seems after he discovers she is part of a smuggling ring; Sarah faces her jealousy.

Though originally presumed dead, Bryce returns...

Though originally presumed dead, Bryce returns at Thanksgiving and needs Chuck’s help to prove he isn’t a rogue.

For his latest mission, Chuck has to pose...

For his latest mission, Chuck has to pose as Sarah’s husband while trying to stifle his true, unrequited feelings for her.

Chuck urges Casey to fight for the woman...

Chuck urges Casey to fight for the woman he loves before she marries a Russian arms dealer holding secret meetings in Los Angeles.

Captain Awesome’s engagement ring is stolen...

Captain Awesome’s engagement ring is stolen when Buy More is robbed; Chuck has to be relocated before the CIA discovers him.

Chuck's sister throws him a party to help...

Chuck's sister throws him a party to help him meet more women.

Chuck gets more than he bargained for when...

Chuck gets more than he bargained for when he opens an email from his college roommate Bryce.

Sarah's date with Chuck is interrupted when...

Sarah's date with Chuck is interrupted when she has to fight of NSA agents who are after him.

Chuck unknowingly tangos with a deadly assassin...

Chuck unknowingly tangos with a deadly assassin until he flashes on her.

KC saves Chuck from an attacker while Sarah...

KC saves Chuck from an attacker while Sarah fights an assassin.

Sarah and KC fight a triad gang in the kitchen...

Sarah and KC fight a triad gang in the kitchen of a restaurant while Chuck tries to hide.

While trying to diffuse a bomb Chuck and...

While trying to diffuse a bomb Chuck and Sarah kiss thinking they're about to die.

During an awkward lunch with Anna's parents,...

During an awkward lunch with Anna's parents, Morgan gets the wrong idea about Sarah when he spots her with another guy.

Captain Awesome asks Chuck for his blessing...

Captain Awesome asks Chuck for his blessing and safe-keeping of his engagement ring.

Sarah disobeys orders to try saving Chuck...

Sarah disobeys orders to try saving Chuck who is being taken to a secret facility.